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17025-uncertainty-measurement-chemical

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  • Uncertainty - a parameter, associated with the result of a measurement, that characterizes the dispersion of the values that could reasonably be attributed to the quantity being measured.
  • Type A evaluation of uncertainty - quantification of uncertainty component using statistical methods.
  • Type B evaluation - quantification of uncertainty component using non-statistical methods.
  • Standard uncertainty - standard deviation associated with a single component of uncertainty.
  • Sensitivity coefficient - coefficient showing the relationship between a single uncertainty component and the standard deviation of a result.
  • Combined standard uncertainty - standard deviation associated with the result of a particular measurement or series of measurements that takes into account one or more components of uncertainty.
  • Expanded uncertainty - combined standard uncertainty multiplied by an appropriate critical value from the t-distribution which depends upon the degrees of freedom in the combined standard uncertainty and the desired level of coverage.
  • Effective degrees of freedom - degrees of freedom associated with a standard deviation composed of two or more components of variance and computed using the Welch-Satterthwaite approximation.
  • Level-1 standard deviation - repeatability standard deviation describing the distribution of short-term measurements under repeatability conditions.
  • Level-2 standard deviation - standard deviation describing the distribution of measurement results over intermediate time-intervals such as day-to-day.

Note - this standard deviation is a function of the between-day standard deviation and the repeatability standard deviation.

  • Level-3 standard deviation - standard deviation describing the distribution of measurement results over the long-term such as run-to-run.

Note - this standard deviation is a function of the between-run standard deviation, the between-day standard deviation and the repeatability standard deviation.

  • Between-day standard deviation - standard deviation describing the distribution of intermediate-term (day-to-day) fluctuations in the measurement process.
  • Between-run standard deviation - standard deviation describing the distribution of long-term (run-to-run) fluctuations in the measurement process.

 

Normative references for this document are:

  • ISO 3534-Part 1: General vocabulary
  • ISO 3435-Part 2: Statistical terms
  • ISO 3435-Part 3: Design of experiments
  • ISO 5725-Part 1: Accuracy of measurement methods and results: General principles and definitions
  • ISO 5725-Part 2: Accuracy of measurement methods and results: Basic method for the determination of repeatability and reproducibility of a standard measurement method
  • ISO 5725-Part 3: Accuracy of measurement methods and results: Intermediate measures of precision of a standard measurement method
  • ISO 5725-Part 4: Accuracy of measurement methods and results: Basic methods for the determination of trueness of a standard measurement method
  • ISO 5725-Part 5: Accuracy of measurement methods and results: Alternative methods for the determination of the precision of a standard measurement method
  • ISO 5725-Part 6: Accuracy of measurement methods and results: Use in practice of accuracy values

ISO 11095: Linear calibration using reference materials

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